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Suppressing Electron Back‐Donation for a Highly CO‐tolerant Fuel Cell Anode Catalyst via Cobalt Modulation

Authors :
Yu Yang
Fei‐Yue Gao
Xiao‐Long Zhang
Shuai Qin
Li‐Rong Zheng
Ye‐Hua Wang
Jie Liao
Qing Yang
Min‐Rui Gao
Source :
Angewandte Chemie. 134
Publication Year :
2022
Publisher :
Wiley, 2022.

Abstract

Platinum on carbon (Pt/C) catalyst is commercially adopted in fuel cells but it undergoes formidable active-site poisoning by carbon monoxide (CO). In particular, given the sluggish kinetics of hydrogen oxidation reaction (HOR) in anion-exchange membrane fuel cell (AEMFC), the issues of Pt poisoning and slow rate would combine mutually, notably worsening the device performances. Here we overcome these challenges through incorporating cobalt (Co) into molybdenum-nickel alloy (MoNi

Details

ISSN :
15213757 and 00448249
Volume :
134
Database :
OpenAIRE
Journal :
Angewandte Chemie
Accession number :
edsair.doi.dedup.....4878a9d0148eaff6586b0789be1179ba