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Strontium Oxide Deposited onto a Load-Bearable and Porous Titanium Matrix as Dynamic and High-Surface-Contact-Area Catalysis for Transesterification

Authors :
Jiunn Der Liao
Bernard Haochih Liu
Yung Der Juang
Mu Hsuan Lee
Wei En Fu
Han Lee
Kundan Sivashanmugan
Source :
Nanomaterials, Vol 8, Iss 12, p 973 (2018), Nanomaterials, Volume 8, Issue 12
Publication Year :
2018
Publisher :
MDPI AG, 2018.

Abstract

Strontium oxide (SrO) deposited onto a porous titanium (Ti)-based scaffold (P-Ti) is a promising and novel approach for high-throughput transesterification. Notably, a highly porous and calcinated scaffold provides a load-bearable support for a continuous process, while the calcinated SrO catalyst, as it is well distributed inside the porous matrix, can extend its surface contact area with the reactant. In this work, the formation of transesterification reaction with the conversion and production of olive oil to biodiesel inside the porous matrix is particularly examined. The as-designed SrO-coated porous titanium (Ti)-based scaffold with 55% porosity was prepared via a hydrothermal procedure, followed by a dip coating method. Mechanical tests of samples were conducted by a nanoindentator, whereas the physical and chemical structures were identified by IR and Raman Spectroscopies. The results implied that SrO catalysts can be firmly deposited onto a load-bearable, highly porous matrix and play an effective role for the transesterification reaction with the oil mass. It is promising to be employed as a load-bearable support for a continuous transesterification process, such as a process for batch or continuous biodiesel production, under an efficient heating source by a focused microwave system.

Details

Language :
English
ISSN :
20794991
Volume :
8
Issue :
12
Database :
OpenAIRE
Journal :
Nanomaterials
Accession number :
edsair.doi.dedup.....48153e25bd663fd93b50ee6656ca1d99