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Smectic A mesophases from luminescent sandic platinum(II) mesogens

Authors :
Venkatesan, Koushik
Kouwer, Paul H. J.
Swager, Timothy M.
Krikorian, Markrete
Voll, Constantin-Chri Alexander
Yoon, Maryam A.
Swager, Timothy M
University of Zurich
Swager, Timothy M
Massachusetts Institute of Technology. Department of Chemistry
Krikorian, Markrete
Voll, Constantin-Chri Alexander
Yoon, Maryam A.
Source :
Liquid Crystals, 43, 1709-1713, Liquid Crystals, 43, 12, pp. 1709-1713, Prof. Swager via Erja Kajosalo
Publication Year :
2016

Abstract

Square planar platinum(II) thienyl pyridyl complexes with board-shaped structures assemble into lamellar (SmA) liquid crystal phases at elevated temperatures. Liquid crystals of this type are expected to have stronger biaxial correlations than typical calamitic mesogens. The mesophase stability improves with decreasing alkyl chain lengths with C₈H₁₇ having the widest range of stability. All complexes are luminescent in solution.<br />National Science Foundation (U.S.) (Grant DMR-1410718)

Details

Language :
English
ISSN :
17091713 and 02678292
Database :
OpenAIRE
Journal :
Liquid Crystals, 43, 1709-1713, Liquid Crystals, 43, 12, pp. 1709-1713, Prof. Swager via Erja Kajosalo
Accession number :
edsair.doi.dedup.....472c52d03d9de2153b2fa42c43740d93
Full Text :
https://doi.org/10.5167/uzh-134647