Addition of benzoyl radicals to butyl acrylate: Absolute rate constants by time-resolved EPR

Authors :: Jean-Luc Birbaum
Kurt Dietliker
Anton Savitsky
Iwo Gatlik
Georg Gescheidt
Daniela Hristova
Klaus Möbius
Günther Rist
Jean-Pierre Wolf
Source :: ResearcherID
Abstract: The addition rate constants of five differently substituted benzoyl radicals to butyl acrylate were determined by continuous-wave time-resolved EPR (TR-EPR at X-band (9 GHz) and at W-band (95 GHz)) spectroscopy. Remarkably, the reactivity of the benzoyl radicals, is divided into two domains: One is established at low (

Subjects :: chemistry.chemical_classification
Addition reaction
Polymers and Plastics
Alkene
Butyl acrylate
Radical
Organic Chemistry
Solution polymerization
Photochemistry
law.invention
Inorganic Chemistry
chemistry.chemical_compound
Reaction rate constant
chemistry
law
Materials Chemistry
Physical chemistry
Reactivity (chemistry)
Electron paramagnetic resonance

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