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Syntheses of metallabenzynes from an allenylcarbene complex
- Source :
- Journal of the American Chemical Society. 127(9)
- Publication Year :
- 2005
-
Abstract
- Treatment of the allenylcarbene complex OsCl2(=CPh-CH=C=CHPh)(PPh3)2 with (PPh3)AuCCR in the presence of HNEt3Cl in CH2Cl2 produces osmabenzynes Os(CC(R)=C(CH2Ph)CH=CPh)Cl2(PPh3)2.
Details
- ISSN :
- 00027863
- Volume :
- 127
- Issue :
- 9
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....46fd5112961d1f175bc396b40e94fc23