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Slow stretched-exponential and fast compressed-exponential relaxation from local event dynamics

Authors :
Alessio Zaccone
Kostya Trachenko
Trachenko, K [0000-0003-4832-7101]
Zaccone, A [0000-0002-6673-7043]
Apollo - University of Cambridge Repository
Publication Year :
2021
Publisher :
Apollo - University of Cambridge Repository, 2021.

Abstract

We propose an atomistic model for correlated particle dynamics in liquids and glasses predicting both slow stretched-exponential relaxation (SER) and fast compressed-exponential relaxation (CER). The model is based on the key concept of elastically interacting local relaxation events. SER is related to slowing down of dynamics of local relaxation events as a result of this interaction, whereas CER is related to the avalanche-like dynamics in the low-temperature glass state. The model predicts temperature dependence of SER and CER seen experimentally and recovers the simple, Debye, exponential decay at high temperature. Finally, we reproduce SER to CER crossover across the glass transition recently observed in metallic glasses.

Details

Database :
OpenAIRE
Accession number :
edsair.doi.dedup.....466bdf455cb37bc506fabd6924e86b17
Full Text :
https://doi.org/10.17863/cam.71423