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Thermometric titration in investigation of the formation of polyanions of molybdenum(VI), tungsten(VI), vanadium(V), and chromium (VI)—IComparison of thermometric and potentiometric titration curves
Thermometric titration in investigation of the formation of polyanions of molybdenum(VI), tungsten(VI), vanadium(V), and chromium (VI)—IComparison of thermometric and potentiometric titration curves
- Source :
- Talanta. 20:875-884
- Publication Year :
- 1973
- Publisher :
- Elsevier BV, 1973.
-
Abstract
- A new twin-cell thermometric titrator has been devised and used for thermometric titration of solutions of sodium molybdate, sodium tungstate, sodium orthovanadate, ammonium metavanadate, and potassium chromate with perchloric acid. The thermometric titration curves were compared with corresponding pH-titration curves for elucidation of the reactions occurring in the titrations. Thermometric titrimetric methods have been developed for the determination of tungsten, vanadium and chromium.
Details
- ISSN :
- 00399140
- Volume :
- 20
- Database :
- OpenAIRE
- Journal :
- Talanta
- Accession number :
- edsair.doi.dedup.....44c63ef2f88905b96a7ca44bca69c1f0
- Full Text :
- https://doi.org/10.1016/0039-9140(73)80203-6