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Glycidyl alkoxysilane reactivities towards simple nucleophiles in organic media for improved molecular structure definition in hybrid materials
- Source :
- RSC Advances, RSC Advances, Royal Society of Chemistry, 2016, 6 (78), pp.74087-74099. ⟨10.1039/c6ra01658h⟩
- Publication Year :
- 2016
- Publisher :
- HAL CCSD, 2016.
-
Abstract
- For hybrid materials, the relationship between the macroscopic properties and the molecular structures and dynamics at the microscopic between the organic and inorganic components level is crucial. The characterization of these components as well as their reactivity have to be emphasized in order to design and synthesize improved hybrids. We report herein the first comprehensive study of the reactivity in organic media of (3-glycidyloxypropyl)trialkoxysilanes, widely used as precursors in sol–gel hybrid synthesis, towards common nucleophiles. Thorough investigations of the reactions allowed us to draw clear conclusions about the reactivities of both epoxide and alkoxysilane functions. Furthermore, the nucleophile properties and the method of activations have a great influence on the reaction outcomes, and unexpected results were found in some cases. The importance of the nature of the alkoxy residues (methoxy, ethoxy…) was also investigated highlighting chemoselective reactions on glycidyl silane derivatives (GPTMS, GPTES and PECS) and opening a new library of original sol–gel precursors.
- Subjects :
- General Chemical Engineering
Epoxide
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Silane
0104 chemical sciences
Characterization (materials science)
chemistry.chemical_compound
chemistry
Nucleophile
Alkoxy group
[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]
Molecule
Organic chemistry
Reactivity (chemistry)
0210 nano-technology
Hybrid material
ComputingMilieux_MISCELLANEOUS
Subjects
Details
- Language :
- English
- ISSN :
- 20462069
- Database :
- OpenAIRE
- Journal :
- RSC Advances, RSC Advances, Royal Society of Chemistry, 2016, 6 (78), pp.74087-74099. ⟨10.1039/c6ra01658h⟩
- Accession number :
- edsair.doi.dedup.....43690e8ddbfd25b2e7137396b168e5cc