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The First Total Synthesis of Tanzawaic Acid B
- Publication Year :
- 2023
- Publisher :
- American Chemical Society (ACS), 2023.
-
Abstract
- The first total synthesis of (+)-tanzawaic acid B, a natural polyketide bearing a pentadienoic ester and octalin moiety, has been accomplished. The synthetic improvement from previous synthetic conditions facilitated our gram-scale synthesis of the chiral octalin that possesses seven stereogenic centers and that is the core skeleton of almost all of the tanzawaic acid family.
Details
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....4249a5ab572487b512014065a57b3520