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An Oxidative [2,3]-Sigmatropic Rearrangement of Allylic Hydrazides
- Source :
- Journal of the American Chemical Society. 133:14252-14255
- Publication Year :
- 2011
- Publisher :
- American Chemical Society (ACS), 2011.
-
Abstract
- The development of an efficient oxidative [2,3]-sigmatropic rearrangement of allylic hydrazides, via singlet N-nitrene intermediates, is reported. The requisite allylic hydrazide precursors are readily prepared and undergo smooth sigmatropic rearrangement upon exposure to iodosobenzene. The products of this novel transformation are shown to be useful precursors to a variety of compounds.
- Subjects :
- Iodosobenzene
Allylic rearrangement
Chemistry
organic chemicals
2,3-sigmatropic rearrangement
food and beverages
General Chemistry
Oxidative phosphorylation
Sigmatropic reaction
Hydrazide
Biochemistry
Medicinal chemistry
Catalysis
chemistry.chemical_compound
Colloid and Surface Chemistry
Singlet state
Subjects
Details
- ISSN :
- 15205126 and 00027863
- Volume :
- 133
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....413963f2c7d32b91c0bd21aa77fedc22