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One-pot synthesis of various Ag–Au bimetallic nanoparticles with tunable absorption properties at room temperature
- Source :
- Gold Bulletin. 46:185-193
- Publication Year :
- 2013
- Publisher :
- Springer Science and Business Media LLC, 2013.
-
Abstract
- This report describes the formation of gold-coated silver bimetallic nanoparticles prepared by the one-pot synthetic approach which involves the subsequent reduction of silver and gold ions at ambient conditions. The reduction of silver ions by excess L-ascorbic acid initially led to the formation of silver cores. This step was followed by the addition of gold ions into the preformed cores, resulting in the formation of silver-core gold-shell type bimetallic nanoparticles at room temperature. This process systematically allowed for the formation of various bimetallic nanoparticles which exhibited tunable absorption properties corresponding to the visible and near-IR regions. The thickness of the gold shells and the diameter of the silver-core nanoparticles were readily controlled; the morphological and structural properties of the resulting bimetallic nanoparticles were thoroughly analyzed by SEM/TEM, DLS, and UV–Vis spectrophotometry. The overall results demonstrated not only that these gold-coated silver nanoparticles were reliably prepared by our one-pot synthetic approach, but also that their optical properties were tunable in the visible and near-IR areas as a function of the core size and shell thickness.
Details
- ISSN :
- 21907579
- Volume :
- 46
- Database :
- OpenAIRE
- Journal :
- Gold Bulletin
- Accession number :
- edsair.doi.dedup.....400d642c433eec1299b4c0d7dc9ad13a