Back to Search Start Over

Cross polarization from H-1 to quadrupolar Li-6 nuclei for dissolution DNP

Authors :
Basile Vuichoud
Geoffrey Bodenhausen
Angel J. Perez Linde
Jonas Milani
Sami Jannin
Aurélien Bornet
Roberto Melzi
Institut des sciences et d'ingénierie chimiques (ISIC)
Ecole Polytechnique Fédérale de Lausanne (EPFL)
Institut des Sciences et Ingénierie Chimiques
Ecole Polytechnique Fédérale de Lausanne (EPFL)-Batochime
Université Pierre et Marie Curie - Paris 6 (UPMC)
Swiss National Science Foundation (SNSF)
Ecole Polytechnique Federale de Lausanne (EPFL)
Swiss Commission for Technology and Innovation (CTI)
French CNRS
European Research Council (ERC) [339754]
Source :
Physical Chemistry Chemical Physics, Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2014, 16 (45), pp.24813-24817. ⟨10.1039/c4cp03592e⟩, Physical chemistry chemical physics : PCCP, Physical Chemistry Chemical Physics, 2014, 16 (45), pp.24813-24817. ⟨10.1039/c4cp03592e⟩
Publisher :
Royal Society of Chemistry

Abstract

International audience; Cross polarization from protons to quadrupolar Li-6 nuclei is combined with dynamic nuclear polarization of protons at 1.2 K and 6.7 T using TEMPOL as a polarizing agent followed by rapid dissolution. Compared to direct Li-6 DNP without cross-polarization, a higher nuclear spin polarization P(Li-6) can be obtained in a shorter time. A double resonance H-1-Li-6 probe was designed that is equipped for Longitudinally Detected Electron Spin Resonance.

Details

ISSN :
14639076 and 14639084
Database :
OpenAIRE
Journal :
Physical Chemistry Chemical Physics, Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2014, 16 (45), pp.24813-24817. ⟨10.1039/c4cp03592e⟩, Physical chemistry chemical physics : PCCP, Physical Chemistry Chemical Physics, 2014, 16 (45), pp.24813-24817. ⟨10.1039/c4cp03592e⟩
Accession number :
edsair.doi.dedup.....3dd7b4705b130234ab1aaee4888ac910
Full Text :
https://doi.org/10.1039/c4cp03592e⟩