Nanostructured Hypercrosslinked Porous Organic Polymers: Morphological Evolution and Rapid Separation of Polar Organic Micropollutants

Nanostructured hypercrosslinked porous organic polymers have triggered immense research interest for a broad spectrum of applications ranging from catalysis to molecular separation. However, it still remains a challenge to tune their nanoscale morphology. Herein, we demonstrated a remarkable variation of morphologies of triptycene-based hypercrosslinked microporous polymers starting from irregular aggregates (FCTP) to rigid spheres (SCTP) to two-dimensional nanosheets (SKTP) from three distinct polymerization methodologies, Friedel-Crafts knitting using an external crosslinker, Scholl reaction, and solvent knitting, respectively. Further, the dramatic role of reaction temperatures, catalysts, and solvents resulting in well-defined morphologies was elucidated. Mechanistic investigations coupled with microscopic and computational studies revealed the evolution of 2D nanosheets of a highly porous solvent-knitted polymer (SKTP, 2385 m