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Nanocomposite Nb-Al-N coatings: Experimental and theoretical principles of phase transformations
- Source :
- Journal of Alloys and Compounds. 718:260-269
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- Phase transformations of Al doped NbN nanocomposite coatings are studied in detail focusing on their microstructural evolution and phase composition. Several techniques such as XRD, SEM, HR-TEM, Nanoindentation and molecular dynamics simulation are employed in order to understand the phase evolution of the Nb-Al-N system. The nanocomposite structures were formed in the coatings, the roughness of the coatings decreased with increasing the Al concentration due to decreasing grain size. First-principles investigation of Nb-Al-N solid solutions was carried out to interpret film properties. It was found, that for small Al fractions, the solid solutions will form in agreement with our experimental results. The spinodal decomposition of Nb-Al-N solid solutions is supposed to be responsible for the formation of the nanocomosite structure observed in the deposited Nb-Al-N films.
- Subjects :
- Materials science
Spinodal decomposition
Mechanical properties
02 engineering and technology
01 natural sciences
Nanocomposites
Phase (matter)
0103 physical sciences
Materials Chemistry
Microstructure
010302 applied physics
Nanocomposite
Mechanical Engineering
Doping
Metallurgy
Metals and Alloys
Computational modeling
Metals and alloys
Nanoindentation
021001 nanoscience & nanotechnology
Grain size
Chemical engineering
Mechanics of Materials
C-PVD
0210 nano-technology
Solid solution
Subjects
Details
- ISSN :
- 09258388
- Volume :
- 718
- Database :
- OpenAIRE
- Journal :
- Journal of Alloys and Compounds
- Accession number :
- edsair.doi.dedup.....3c5a5d8c1a9239d9deb43a26efc527de