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Iron(ii) coordination polymer catalysed hydroboration of ketones
- Source :
- Dalton transactions (Cambridge, England : 2003). 47(29)
- Publication Year :
- 2018
-
Abstract
- Catalytic hydroboration of ketones with pinacolborane was achieved with a 2D iron(ii) coordination polymer (CP) of a divergent 4,2';6',4''-terpyridine (tpy) derivative under mild conditions with high efficiency. This solid iron catalyst system is more active towards the hydroboration of ketones than that of aldehydes, displaying a different trend of reactivity from known homogeneous iron hydroboration catalysts.
- Subjects :
- 010405 organic chemistry
Coordination polymer
010402 general chemistry
01 natural sciences
0104 chemical sciences
Catalysis
Inorganic Chemistry
chemistry.chemical_compound
Hydroboration
chemistry
Homogeneous
Polymer chemistry
Reactivity (chemistry)
Terpyridine
Iron catalyst
Derivative (chemistry)
Subjects
Details
- ISSN :
- 14779234
- Volume :
- 47
- Issue :
- 29
- Database :
- OpenAIRE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Accession number :
- edsair.doi.dedup.....39ae8bed9a562d918d4d5a423e48b97a