Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

Authors :: Mireia Sidera
Ruchuta Ardkhean
Özlem Sari
Robert S. Paton
Stephen P. Fletcher
Timothy D. W. Claridge
Lucy van Dijk
Sedef Karabiyikoglu
Publication Year :: 2020
Publisher :: American Chemical Society (ACS), 2020.
Abstract: A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations.

Subjects :: Quantum chemical
Coupling (electronics)
Reaction mechanism
chemistry
Computational chemistry
Kinetic isotope effect
Enantioselective synthesis
chemistry.chemical_element
Allyl halides
Rhodium
Catalysis

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