Back to Search
Start Over
Pd-catalysed, Ag-assisted C2-H alkenylation of benzophospholes
- Source :
- Chemical communications (Cambridge, England). 58(87)
- Publication Year :
- 2022
-
Abstract
- A palladium-catalysed, silver-assisted regioselective C2-H alkenylation of benzophospholes with terminal alkenes has been developed. The palladium catalysis accommodates styrenes and electron-deficient alkenes including ester, ketone, nitrile, and phosphonate. Thus, this protocol enables the rapid construction of various benzophosphole-vinylene conjugations from the two simple C-H starting substrates. Optical properties of newly synthesized C2-alkenylated benzophospholes are also investigated.
Details
- ISSN :
- 1364548X
- Volume :
- 58
- Issue :
- 87
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....37b61031a321811a172404ca5d59b334