Equiaxed Grain Formation by Intrinsic Heterogeneous Nucleation Via Rapid Heating and Cooling in Additive Manufacturing of Aluminum-Silicon Hypoeutectic Alloy

Masayuki Okugawa, Yuta Ohigashi, Yuya Furishiro, Yuichiro Koizumi, Takayoshi Nakano, Equiaxed grain formation by intrinsic heterogeneous nucleation via rapid heating and cooling in additive manufacturing of aluminum-silicon hypoeutectic alloy, Journal of Alloys and Compounds, Volume 919, 2022, 165812, ISSN 0925-8388, https://doi.org/10.1016/j.jallcom.2022.165812.
The high strength of Al-Si hypoeutectic alloys additively manufactured by powder-bed fusion is of great scientific interest. To date, the mechanism of grain refinement near the fusion line, which contradicts conventional Hunt's columnar–equiaxed transition criteria, remains to be elucidated. Here we present the first report on the mechanism of grain refinement. When a laser was irradiated on cast Al-Si alloy consisting of coarse α-Al grain and α-Al/Si eutectic regions, grain refinement occurred only near the eutectic regions. This strongly suggests that the Si phase is crucial for grain refinement. Multi-phase-field simulation revealed that rapid heating due to the laser irradiation results in unmelted Si particles even above the liquidus temperature and that the particles act as heterogeneous nucleation sites during the subsequent re-solidification. These results suggest the feasibility of a novel inoculant-free grain refinement that is applicable to eutectic alloys comprising phases with a significant melting point difference.