Understanding fast-ion conduction in solid electrolytes

The ability of some solid materials to exhibit exceptionally high ionic conductivities has been known since the observations of Michael Faraday in the nineteenth century (Faraday M. 1838Phil. Trans. R. Soc.90), yet a detailed understanding of the atomic-scale physics that gives rise to this behaviour remains an open scientific question. This theme issue collects articles from researchers working on this question of understanding fast-ion conduction in solid electrolytes. The issue opens with two perspectives, both of which discuss concepts that have been proposed as schema for understanding fast-ion conduction. The first perspective presents an overview of a series of experimental NMR studies, and uses this to frame discussion of the roles of ion–ion interactions, crystallographic disorder, low-dimensionality of crystal structures, and fast interfacial diffusion in nanocomposite materials. The second perspective reviews computational studies of halides, oxides, sulfides and hydroborates, focussing on the concept offrustrationand how this can manifest in different forms in various fast-ion conductors. The issue also includes five primary research articles, each of which presents a detailed analysis of the factors that affect microscopic ion-diffusion in specific fast-ion conducting solid electrolytes, including oxide-ion conductorsGd2Zr2O7andBi4V2O11, lithium-ion conductorsLi6PS5BrandLi3OCl, and the prototypical fluoride-ion conductorβ-PbF2.This article is part of the Theo Murphy meeting issue ‘Understanding fast-ion conduction in solid electrolytes’.