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Mild Preparation of Alkenes from Phenyl Sulfides: One-Pot Elimination of Phenylthio Group via Sulfilimine at Ambient Temperature

Authors :
Jun-ichi Matsuo
Hiroyuki Ishibashi
Takaaki Kozai
Source :
ChemInform. 38
Publication Year :
2007
Publisher :
Wiley, 2007.

Abstract

[Structure: see text] Various alkenes were prepared from phenyl sulfides in a one-pot manner at room temperature by converting them to the corresponding S-aminosulfonium salts with O-mesitylenesulfonylhydroxylamine, followed by treatment with potassium carbonate. Alkenes were formed by cis-elimination of in situ generated phenyl sulfilimines.

Details

ISSN :
15222667 and 09317597
Volume :
38
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi.dedup.....3449377a6123504c12b81f9f45298728
Full Text :
https://doi.org/10.1002/chin.200717044