Stress−strain behavior of a polyurea and a polyurethane from low to high strain rates

The large deformation stress–strain behavior of thermoplastic–elastomeric polyurethanes and elastomeric-thermoset polyureas is strongly dependent on strain rate. Their mechanical behavior at very high strain rates is of particular interest due to their role as a protective coating on structures to enhance structural survivability during high rate loading events. Here we report on the uniaxial compression stress–strain behavior of a representative polyurea and a representative polyurethane over a wide range in strain rates, from 0.001 s−1 to 10,000 s−1, successively marching through each order of magnitude in strain rate using equipment relevant for testing at each particular rate. These results are further analyzed in association with recently reported compressive data on the same materials by Yi et al. [Polymer 2006;47(1):319–29] and intermediate rate tensile data on the same polyurea by Roland et al. [Polymer 2007;48(2):574–8]. The polyurea tested is seen to undergo transition from a rubbery-regime behavior at low rates to a leathery-regime behavior at the highest rates, consistent with the earlier compression study as well as the recent tension study; the polyurethane tested is observed to undergo transition from a rubbery-regime behavior at the low rates to a glassy behavior at the highest rates. The uniaxial compression data for the polyurea are found to be fully consistent with the recently reported uniaxial tension data over the range of rates studied, demonstrating the consistency and complementary aspects of testing at high rates in both compression and tension.