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Interface control of a morphotropic phase boundary in epitaxial samarium modified bismuth ferrite superlattices
Interface control of a morphotropic phase boundary in epitaxial samarium modified bismuth ferrite superlattices
- Source :
- Physical Review B. 90
- Publication Year :
- 2014
- Publisher :
- American Physical Society (APS), 2014.
-
Abstract
- Interfacial control of a polar-(rhombohedral) to-non-polar (orthorhombic) phase transition in (001)-oriented epitaxial $\mathrm{BiFe}{\mathrm{O}}_{3}\text{/}(\mathrm{B}{\mathrm{i}}_{1\ensuremath{-}x}\mathrm{S}{\mathrm{m}}_{x})\mathrm{Fe}{\mathrm{O}}_{3}$ superlattices is presented. We demonstrate controlling the composition at which a polar phase transformation takes place by tuning the strength of the interlayer interactions while holding the average composition constant. It is shown that the thickness of the superlattice layers has a strong influence on the interlayer polar coupling, which in turn changes the phase transition. For the shortest periods studied (layers 5- and 10-nm thick) the onset of the phase transition is suppressed along with a significant broadening (as a function of $\mathrm{S}{\mathrm{m}}^{3+}$ concentration) of an incommensurately modulated phase determined by two-dimensional x-ray diffraction mapping. Consequently, a ferroelectric character with robust polarization hysteresis and enhanced dielectric constant is observed even for substitution concentration of $\mathrm{S}{\mathrm{m}}^{3+}$ which would otherwise lead to a leaky paraelectric in single-layer $(\mathrm{B}{\mathrm{i}}_{1\ensuremath{-}x}\mathrm{S}{\mathrm{m}}_{x})\mathrm{Fe}{\mathrm{O}}_{3}$ films. The experimental results are fully consistent with a mean-field thermodynamic theory which reveals that the strength of the interlayer coupling is strongly affected by the polar-polar interaction across the interface.
- Subjects :
- Phase boundary
Phase transition
Materials science
Superlattice
chemistry.chemical_element
Dielectric
Condensed Matter Physics
Ferroelectricity
Electronic, Optical and Magnetic Materials
Samarium
Condensed Matter::Materials Science
Crystallography
chemistry.chemical_compound
chemistry
Orthorhombic crystal system
Bismuth ferrite
Subjects
Details
- ISSN :
- 1550235X and 10980121
- Volume :
- 90
- Database :
- OpenAIRE
- Journal :
- Physical Review B
- Accession number :
- edsair.doi.dedup.....32b3f4b6a6d070e0b2469fa8968af7ed
- Full Text :
- https://doi.org/10.1103/physrevb.90.245131