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An Integrated Chemiluminescence Microreactor for Ultrastrong and Long‐Lasting Light Emission
- Source :
- Advanced Science, Vol 7, Iss 15, Pp n/a-n/a (2020), Advanced Science
- Publication Year :
- 2020
- Publisher :
- Wiley, 2020.
-
Abstract
- A porous metal–organic framework [Ba(H2 LLOMe 2−)·DMF·H2O]·2DMF (UPC‐2) (H4 LLOMe = 4ʹ,4ʹʹʹ‐(2,3,6,7‐tetramethoxyanthracene‐9,10‐diyl)bis([1,1ʹ‐biphenyl]‐3,5‐dicarbo‐xylic acid N,N‐Dimethylformamide [DMF]), which can act as an excellent chemiluminescence microreactor, is designed and constructed. In the framework of UPC‐2, the catalytic Ba cluster and electron‐rich anthracene fluorescent centers are fixed and interconnected in an orderly fashion, and this can shorten the energy transfer path and weaken the relaxation of the chemiluminescence process. Meanwhile, the rhombic channels of UPC‐2 can provide a proper diffusion ratio of reactants to support a stable and continuous energy supply. The UPC‐2 chemiluminescence microreactor exhibits an ultrastrong and long‐lasting light emission, which possesses potential application in emergency lights and biological mapping. The concept of the chemiluminescence microreactor and its construction using a metal–organic framework as a platform will promote further research in the design and fabrication of functional MOFs for chemiluminescence applications.<br />To enhance the light‐emitting intensity and extend the lasting time of chemiluminescence (CL) reaction, a concept of “integrated chemiluminescence microreactor” is proposed and constructed using a metal–organic framework as a platform. The as‐obtained microreactor presents an ultrahigh light‐emitting intensity which could be observed by the naked eye even after 540 min.
- Subjects :
- Fabrication
Materials science
General Chemical Engineering
General Physics and Astronomy
Medicine (miscellaneous)
02 engineering and technology
010402 general chemistry
Photochemistry
01 natural sciences
Biochemistry, Genetics and Molecular Biology (miscellaneous)
Catalysis
law.invention
metal–organic frameworks
chemistry.chemical_compound
law
General Materials Science
lcsh:Science
Chemiluminescence
Anthracene
Communication
General Engineering
021001 nanoscience & nanotechnology
microreactors
Fluorescence
Communications
chemiluminescence
0104 chemical sciences
chemistry
controlled diffusion
lcsh:Q
Light emission
Metal-organic framework
Microreactor
0210 nano-technology
Subjects
Details
- ISSN :
- 21983844
- Volume :
- 7
- Database :
- OpenAIRE
- Journal :
- Advanced Science
- Accession number :
- edsair.doi.dedup.....3275b1baff738ce768cf78295a8411cd