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Activation of SO2 by [Zn(Cp*)2] and [(Cp*)ZnI–ZnI(Cp*)]
- Source :
- Chemical Communications, Chemical Communications, 2016, 52 (89), pp.13090-13093. ⟨10.1039/c6cc05638e⟩, Chemical Communications, Royal Society of Chemistry, 2016, 52 (89), pp.13090-13093. ⟨10.1039/c6cc05638e⟩
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- International audience; Interesting reactivity was observed in reactions of SO2 with [Zn(Cp*)2] and [(Cp*)ZnI–ZnI(Cp*)]. These reactions proceeded with insertion of SO2 into the Zn–C bonds. Spectacularly, the lability of the C–S bond in the O2SCp* ligands led to the thermal decomposition of [Zn(O2SCp*)2(tmeda)] to afford [Zn2(μ-SO3)(μ-S2O4)(tmeda)2].
- Subjects :
- 010405 organic chemistry
Lability
Chemistry
Thermal decomposition
Metals and Alloys
General Chemistry
010402 general chemistry
01 natural sciences
Medicinal chemistry
Catalysis
3. Good health
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Materials Chemistry
Ceramics and Composites
[CHIM]Chemical Sciences
Reactivity (chemistry)
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 52
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....31b664a86c6850857fd683bcf2419431
- Full Text :
- https://doi.org/10.1039/c6cc05638e