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Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2
- Source :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2016, 52, pp.12905-12908. ⟨10.1039/c6cc05473k⟩, Feng, X, Liu, J-L, Pedersen, K S, Nehrkorn, J, Schnegg, A, Holldack, K, Bendix, J, Sigrist, M, Mutka, H, Samohvalov, D, Aguilà, D, Tong, M-L, Long, J R & Clérac, R 2016, ' Multifaceted magnetization dynamics in the mononuclear complex [Re IV Cl 4 (CN) 2 ] 2-', Chemical Communications, vol. 52, no. 87, pp. 12905-12908 . https://doi.org/10.1039/c6cc05473k, 'Chemical Communications ', vol: 52, pages: 12905-12908 (2016)
- Publication Year :
- 2016
- Publisher :
- HAL CCSD, 2016.
-
Abstract
- International audience; The mononuclear complex (Bu4N)2[ReIVCl4(CN)2].2DMA (DMA =N,N-dimethylacetamide) displays intricate magnetization dynamics, implying Orbach, direct, and Raman-type relaxation processes. The Orbach relaxation process is characterized by an energy barrier of 39 K (27 cm-1) that is discussed based on high-field electron paramagnetic resonance (EPR), inelastic neutron scattering and frequency domain THz EPR investigations.
- Subjects :
- Magnetization dynamics
010405 organic chemistry
Chemistry
Relaxation (NMR)
Metals and Alloys
Relaxation process
Large scale facilities for research with photons neutrons and ions
General Chemistry
[CHIM.MATE]Chemical Sciences/Material chemistry
010402 general chemistry
01 natural sciences
Catalysis
Inelastic neutron scattering
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
law.invention
Nuclear magnetic resonance
law
Chemical physics
Materials Chemistry
Ceramics and Composites
Electron paramagnetic resonance
Subjects
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Database :
- OpenAIRE
- Journal :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2016, 52, pp.12905-12908. ⟨10.1039/c6cc05473k⟩, Feng, X, Liu, J-L, Pedersen, K S, Nehrkorn, J, Schnegg, A, Holldack, K, Bendix, J, Sigrist, M, Mutka, H, Samohvalov, D, Aguilà, D, Tong, M-L, Long, J R & Clérac, R 2016, ' Multifaceted magnetization dynamics in the mononuclear complex [Re IV Cl 4 (CN) 2 ] 2-', Chemical Communications, vol. 52, no. 87, pp. 12905-12908 . https://doi.org/10.1039/c6cc05473k, 'Chemical Communications ', vol: 52, pages: 12905-12908 (2016)
- Accession number :
- edsair.doi.dedup.....2fc0c49ecea4e166cbee93755761bbf7