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Bis[1,2-bis(dimethylphosphino)ethane]dichloridonitrosyltungsten(0) chloride

Authors :
Heinz Berke
Helmut W. Schmalle
Olivier Blacque
Nataša Avramović
University of Zurich
Blacque, O
Source :
Acta Crystallographica Section E, Vol 64, Iss 1, Pp m245-m245 (2008), Acta Crystallographica Section E: Structure Reports
Publication Year :
2008
Publisher :
Wiley-Blackwell, 2008.

Abstract

In the crystal structure of the title compound, [WCl(2)(NO)(C(6)H(16)P(2))(2)]Cl, the seven-coordinated tungsten(II) center displays a distorted penta-gonal-bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4.

Details

Database :
OpenAIRE
Journal :
Acta Crystallographica Section E, Vol 64, Iss 1, Pp m245-m245 (2008), Acta Crystallographica Section E: Structure Reports
Accession number :
edsair.doi.dedup.....2f5b5a8aa11bbcf95cf98457a57064f7
Full Text :
https://doi.org/10.5167/uzh-13212