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Bis(cyanato-κN)bis(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN3)zinc

Authors :
Antonio Rodríguez-Diéguez
Ana B. Caballero
Juan M. Salas
Miguel Quirós
Source :
Acta Crystallographica Section E: Structure Reports
Publication Year :
2011
Publisher :
International Union of Crystallography (IUCr), 2011.

Abstract

In the title complex, [Zn(NCO)(2)(C(7)H(8)N(4))(2)], the Zn(II) ion exhibits a distorted tetra-hedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions inter-acting by their N atoms. Supra-molecular dimers are generated by stacking inter-actions between the pyrimidine rings of two ligands related by an inversion center [centroid-centroid distance = 3.5444 (18) Å].

Details

ISSN :
16005368
Volume :
67
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi.dedup.....2e5131398ae5e7853414a5c7a980fca8