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2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(<scp>v</scp>) oxidant
- Source :
- Chemical сommunications. 2019. Vol. 55, № 54. P. 7760-7763
- Publication Year :
- 2019
- Publisher :
- Royal Society of Chemistry (RSC), 2019.
-
Abstract
- A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
- Subjects :
- гипервалентный йод
010405 organic chemistry
Chemistry
Oxidation resistant
Metals and Alloys
Hypervalent molecule
chemistry.chemical_element
General Chemistry
010402 general chemistry
Iodine
рентгеновская кристаллография
01 natural sciences
Combinatorial chemistry
Catalysis
0104 chemical sciences
3. Good health
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
2-йодоксибензойная кислота
2-Iodoxybenzoic acid
Materials Chemistry
Ceramics and Composites
Single crystal
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 55
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....2da3355e315d70616663aa4d7fd8bd63
- Full Text :
- https://doi.org/10.1039/c9cc04203b