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Reaction Mechanisms for Graphene and Carbon Nanotube Fluorination
- Source :
- Journal of Physical Chemistry C, Journal of Physical Chemistry C, American Chemical Society, 2010, 114 (8), pp.3340. ⟨10.1021/jp908887n⟩
- Publication Year :
- 2010
- Publisher :
- HAL CCSD, 2010.
-
Abstract
- International audience; Via density functional theory calculations, we explore the process of graphene and carbon nanotube fluorination. Contrary to graphene, HF-catalyzed carbon nanotube fluorination adds fluorine pairs at (1,4) spacing, naturally leading to a self-organized C4F coverage, which call subsequently rearrange into dense axial C2F lines by fluorine diffusion upon solubilization or heat treatment. Controlling the fluorination process and subsequent nanotube processing results in fluorinated material types with unexplored electronic and chemical properties.
- Subjects :
- Reaction mechanism
Nanotube
Materials science
Selective chemistry of single-walled nanotubes
chemistry.chemical_element
Nanotechnology
02 engineering and technology
Carbon nanotube
010402 general chemistry
01 natural sciences
law.invention
Condensed Matter::Materials Science
law
Physics::Atomic and Molecular Clusters
Physics::Chemical Physics
Physical and Theoretical Chemistry
Nuclear Experiment
Astrophysics::Galaxy Astrophysics
reaction Mechanisms
Graphene
021001 nanoscience & nanotechnology
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Carbon nanotube quantum dot
General Energy
chemistry
Chemical engineering
Fluorine
[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]
Density functional theory
0210 nano-technology
Subjects
Details
- Language :
- English
- ISSN :
- 19327447 and 19327455
- Database :
- OpenAIRE
- Journal :
- Journal of Physical Chemistry C, Journal of Physical Chemistry C, American Chemical Society, 2010, 114 (8), pp.3340. ⟨10.1021/jp908887n⟩
- Accession number :
- edsair.doi.dedup.....2c4441ad66b7f503d683f2e883f3d523