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Electrochemical Control of Ion Transport through a Mesoporous Carbon Membrane

Authors :
Je Seung Lee
Jai Pil Choi
Ivan Vlassiouk
Sheng Dai
Xiqing Wang
Shannon M. Mahurin
Song-Hai Chai
Sumedh P. Surwade
Source :
Langmuir. 30:3606-3611
Publication Year :
2014
Publisher :
American Chemical Society (ACS), 2014.

Abstract

We report a carbon-based, three-dimensional nanofluidic transport membrane that enables gated, or on/off, control of the transport of organic molecular species and metal ions using an applied electrical potential. In the absence of an applied potential, both cationic and anionic molecules freely diffuse across the membrane via a concentration gradient. However, when an electrochemical potential is applied, the transport of ions through the membrane is inhibited.

Details

ISSN :
15205827 and 07437463
Volume :
30
Database :
OpenAIRE
Journal :
Langmuir
Accession number :
edsair.doi.dedup.....2c224640f90e5e361c30101ac4df301a