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{2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)
- Source :
- Acta Crystallographica Section E: Structure Reports
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography (IUCr), 2011.
-
Abstract
- In the title compound, [Co(C(20)H(18)P)I(C(3)H(9)P)(2)], the Co(II) atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe(3) groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five-membered chelated Co-C-C-C-P ring.
- Subjects :
- Metal-Organic Papers
chemistry.chemical_classification
biology
Base (chemistry)
Chemistry
Atom (order theory)
chemistry.chemical_element
General Chemistry
Condensed Matter Physics
biology.organism_classification
Ring (chemistry)
Bioinformatics
Medicinal chemistry
chemistry.chemical_compound
Phos
Benzyl group
General Materials Science
Chelation
Cobalt
Pyramid (geometry)
Subjects
Details
- ISSN :
- 16005368
- Volume :
- 67
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Structure Reports Online
- Accession number :
- edsair.doi.dedup.....2bd911f95a6c48cad50c6df69191931f