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{2-[(Benzylphenylphosphanyl-κP)methyl]phenyl-κC1}iodidobis(trimethylphosphane)cobalt(II)

Authors :
Xiaoyan Li
Chenggen Wang
Jiong Jia
Nazhen Liu
Source :
Acta Crystallographica Section E: Structure Reports
Publication Year :
2011
Publisher :
International Union of Crystallography (IUCr), 2011.

Abstract

In the title compound, [Co(C(20)H(18)P)I(C(3)H(9)P)(2)], the Co(II) atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe(3) groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five-membered chelated Co-C-C-C-P ring.

Details

ISSN :
16005368
Volume :
67
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi.dedup.....2bd911f95a6c48cad50c6df69191931f