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A Strongly Emitting Liquid-Crystalline Derivative of Y3N@C80: Bright and Long-Lived Near-IR Luminescence from a Charge Transfer State
- Publication Year :
- 2013
-
Abstract
- Great balls of fire: C60 and Y3 N@C80 were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y3 N@C80 derivative, and both dyads gave rise to columnar phases with core-shell cylinders. The black and gray spheres represent the fullerene core units of the Y3 N@C80 derivative, which is an ideal candidate to be involved in energy and electron transfer processes.
- Subjects :
- endohedral cluster fullerene
Fullerene
Materials science
010402 general chemistry
Photochemistry
01 natural sciences
Catalysis
Electron transfer
chemistry.chemical_compound
Liquid crystal
Endohedral fullerene
photophysics
010405 organic chemistry
DENSITY FUNCTIONAL CALCULATIONS
metallomesogen
General Medicine
General Chemistry
3. Good health
0104 chemical sciences
Core (optical fiber)
chemistry
Chemical physics
LIQUID CRYSTALS
SPHERES
Luminescence
Derivative (chemistry)
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....2bcc713af0ec6b544b481e6359d1f7b4