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Multi-year inter-laboratory exercises for the analysis of illicit drugs and metabolites in wastewater: Development of a quality control system

Authors :
Zenon J. Kokot
Miren López de Alda
Cobus Gerber
Serge Schneider
Kevin V. Thomas
Erik Emke
María Jesús Andrés-Costa
Frederic Been
Angela Li
Jake W. O'Brien
Despo Fatta-Kassinos
Viviane Yargeau
Adrian Covaci
Sara Castiglioni
Markus R. Meyer
Félix Hernández
Ivona Krizman-Matasic
Roman Grabic
Jerker Fick
Arndis S. C. Love
Jean-Daniel Berset
José Benito Quintana
Jose Antonio Baz-Lomba
Iria González-Mariño
Susana Sadler Simões
Lisa Benaglia
Kurunthachalam Kannan
Daniel A. Burgard
Christoph Ort
Leon Barron
Lubertus Bijlsma
Xiqing Li
Ann Kathrin McCall
Nikolaos S. Thomaidis
Malcolm J. Reid
Christophoros Christophoridis
Alexander L.N. van Nuijs
Sara Karolak
Teemu Gunnar
Pim de Voogt
Foon Yin Lai
Barbara Kasprzyk-Hordern
Herbert Oberacher
European Cooperation in Science and Technology
Ministerio de Economía y Competitividad (España)
Research Foundation - Flanders
Generalitat Valenciana
Xunta de Galicia
Office for Combating Narcotic Drug Abuse (Republic of Croatia)
Generalitat de Catalunya
Natural Sciences and Engineering Research Council of Canada
Ministry of Education, Youth and Sports (Czech Republic)
Swiss National Science Foundation
European Commission
Been, Frederic [0000-0001-5910-3248]
Covaci, Adrian [orcid.org/0000-0003-0527-1136]
Voogt, Pim de [0000-0001-9065-9797]
Emke, Erik [0000-0002-8441-1709]
Fick, Jerker [0000-0002-3949-7371]
Hernández, Félix [0000-0003-1268-3083]
Kasprzyk-Hordern, Barbara [0000-0002-6809-2875]
Li, Xiqing [0000-0002-3162-5068]
López de Alda, Miren [0000-0002-9347-2765]
Quintana, Benito [0000-0002-2566-8133]
Ort, Christoph [0000-0001-9950-2286]
Universidade de Santiago de Compostela. Departamento de Química Analítica, Nutrición e Bromatoloxía
Universidade de Santiago de Compostela. Instituto de Investigación e Análises Alimentarias
Been, Frederic
Covaci, Adrian
Voogt, Pim de
Emke, Erik
Fick, Jerker
Hernández, Félix
Kasprzyk-Hordern, Barbara
Li, Xiqing
López de Alda, Miren
Quintana, Benito
Ort, Christoph
Freshwater and Marine Ecology (IBED, FNWI)
van Nuijs, ALN
Lai, FY
Been, F
Andres-Costa, MJ
Gerber, C
Ort, C
Source :
Digital.CSIC. Repositorio Institucional del CSIC, instname, Repositori Universitat Jaume I, Universitat Jaume I, Trends in analytical chemistry, Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela, van Nuijs, A L N, Lai, F Y, Been, F, Jesus Andres-Costa, M, Barron, L, Baz-Lomba, J A, Berset, J-D, Benaglia, L, Bijlsma, L, Burgard, D, Castiglioni, S, Christophoridis, C, Covaci, A, de Voogt, P, Emke, E, Fatta-Kassinos, D, Fick, J, Hernandez, F, Gerber, C, González-Mariño, I, Grabic, R, Gunnar, T, Kannan, K, Karolak, S, Kasprzyk-Hordern, B, Kokot, Z, Krizman-Matasic, I, Li, A, Li, X, Löve, A S C, Lopez de Alda, M, Meyer, M R, Oberacher, H, O’Brien, J, Benito Quintana, J, Reid, M, Schneider, S, Simoes, S S, Thomaidis, N S, Thomas, K, Yargeau, V & Ort, C 2018, ' Multi-year interlaboratory exercises for the analysis of illicit drugs and metabolites in wastewater : development of a quality control system ', TRENDS IN ANALYTICAL CHEMISTRY . https://doi.org/10.1016/j.trac.2018.03.009, TrAC. Trends in analytical chemistry, Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos), Agência para a Sociedade do Conhecimento (UMIC)-FCT-Sociedade da Informação, instacron:RCAAP, Trends in Analytical Chemistry, Trends in Analytical Chemistry, 103, 34-43. Elsevier
Publication Year :
2018
Publisher :
Elsevier, 2018.

Abstract

Thirty-seven laboratories from 25 countries present the development of an inter-laboratory testing scheme for the analysis of seven illicit drug residues in standard solutions, tap- and wastewater. Almost 10 000 concentration values were evaluated: triplicates of up to five samples and 26 laboratories per year. The setup was substantially improved with experiences gained across the six repetitions (e.g. matrix type, sample conditions, spiking levels). From this, (pre-)analytical issues (e.g. pH adjustment, filtration) were revealed for specific analytes which resulted in formulation of best-practice protocols for inter-laboratory setup and analytical procedures. The results illustrate the effectiveness of the inter-laboratory setup to assess laboratory performance in the framework of wastewater-based epidemiology. The exercise proved that measurements of laboratories were of high quality (>80% satisfactory results for six out of seven analytes) and that analytical follow-up is important to assist laboratories in improving robustness of wastewater-based epidemiology results.<br />This article is based upon work from COST Action ES1307 supported by COST (European Cooperation in Science and Technology). We wish to acknowledge EMCDDA and Yeonsuk Ryu for support in the organization of the scheme and assistance in the preparation of the test samples, respectively. The following funding sources are acknowledged: the Research Foundation – Flanders (FWO) (Grant number: 1285216N), the Spanish Ministry of Economy, Industry and Competitiveness, the Generalitat Valenciana, Xunta de Galicia, Stavros Niarchos Foundation, Office for Combating Narcotic Drug Abuse of the Government of the Republic of Croatia, EU FP7 project SOLUTIONS (603437), the Government of Catalonia, the Natural Sciences and Engineering Research Council of Canada (NSERC), Ministry of Education, Youth and Sports of the Czech Republic (projects CENAKVA and CENAKVA II), EU Marie Skłodowska-Curie Fellowship (APOLLO 749845) and the Swiss National Science Foundation (SNSF, P2LAP2_164892). The following persons are acknowledged for help in sample analysis: Marijan Ahel, Evroula Hapeshi, Popi Karaolia, Esther López-García, Nicola Mastroianni, Cristina Postigo, Inés Racamonde, Rosario Rodil, Isaac Rodríguez, Tania Rodríguez-Álvarez, Ivan Senta, and Senka Terzic.

Details

ISSN :
01659936
Database :
OpenAIRE
Journal :
Digital.CSIC. Repositorio Institucional del CSIC, instname, Repositori Universitat Jaume I, Universitat Jaume I, Trends in analytical chemistry, Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela, van Nuijs, A L N, Lai, F Y, Been, F, Jesus Andres-Costa, M, Barron, L, Baz-Lomba, J A, Berset, J-D, Benaglia, L, Bijlsma, L, Burgard, D, Castiglioni, S, Christophoridis, C, Covaci, A, de Voogt, P, Emke, E, Fatta-Kassinos, D, Fick, J, Hernandez, F, Gerber, C, González-Mariño, I, Grabic, R, Gunnar, T, Kannan, K, Karolak, S, Kasprzyk-Hordern, B, Kokot, Z, Krizman-Matasic, I, Li, A, Li, X, Löve, A S C, Lopez de Alda, M, Meyer, M R, Oberacher, H, O’Brien, J, Benito Quintana, J, Reid, M, Schneider, S, Simoes, S S, Thomaidis, N S, Thomas, K, Yargeau, V & Ort, C 2018, ' Multi-year interlaboratory exercises for the analysis of illicit drugs and metabolites in wastewater : development of a quality control system ', TRENDS IN ANALYTICAL CHEMISTRY . https://doi.org/10.1016/j.trac.2018.03.009, TrAC. Trends in analytical chemistry, Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos), Agência para a Sociedade do Conhecimento (UMIC)-FCT-Sociedade da Informação, instacron:RCAAP, Trends in Analytical Chemistry, Trends in Analytical Chemistry, 103, 34-43. Elsevier
Accession number :
edsair.doi.dedup.....2b3a0a5a0cf639a66f69db5b830b5151