Optical Chemosensors Based on Transmetalation of Salen-Based Schiff Base Complexes

We report our systematic studies of novel, simple, selective, and sensitive optical (both colorimetric and fluorescent) chemosensors for detecting Al(3+) based on transmetalation reactions (metal displacement or exchange reactions) of a series of K(I), Ca(II), Zn(II), Cu(II), and Pt(II) complexes containing different ligands of salen-based Schiff bases. Both the chemical structure of the salen ligand and the identity of the central metal ion have a tremendous impact on the sensing performance, which is mainly determined by the stability constant of the complex. Moreover, the selectivities of the salen-complex-based chemosensors are much better than those of the corresponding free salen ligands because of the shielding function of the filled-in metal ion in the complex. Therefore, the present work potentially provides a new and simple way to design optical probes via complex-based transmetalation reactions.