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EXAFS, Raman and 31P NMR study of amorphous titanium phosphates
- Source :
- Journal of Non-Crystalline Solids, Journal of Non-Crystalline Solids, Elsevier, 1994, 170 (3), pp.250-262. ⟨10.1016/0022-3093(94)90054-X⟩, Journal of Non-Crystalline Solids, 1994, 170 (3), pp.250-262. ⟨10.1016/0022-3093(94)90054-X⟩
- Publication Year :
- 1994
- Publisher :
- Elsevier BV, 1994.
-
Abstract
- The reaction of phosphoric acid with titanium alkoxides for a PO4/Ti ratio ranging from 0.5 to 2 was investigated. For these compositions, amorphous precipitates are obtained. Their microstructure has been studied by means of Raman, nuclear magnetic resonance and X-ray absorption spectroscopies. The phosphatation of titanium alkoxide increases the Ti coordination number to 6 and the symmetry becomes purely octahedral for a P/Ti ratio of 2. For the composition range 0 < PO4/Ti ⩽ 2, phosphate anions are homogeneously dispersed in the precipitate and bound to titanium, the coordination of which is completed by oxo-, hydroxo- and remaining alkoxy- groups. Short TiO distances are observed in the materials having the lowest P/Ti ratios.
- Subjects :
- Materials science
Coordination number
Inorganic chemistry
chemistry.chemical_element
02 engineering and technology
[CHIM.INOR]Chemical Sciences/Inorganic chemistry
010402 general chemistry
01 natural sciences
chemistry.chemical_compound
symbols.namesake
Materials Chemistry
Phosphoric acid
ComputingMilieux_MISCELLANEOUS
Extended X-ray absorption fine structure
[CHIM.MATE]Chemical Sciences/Material chemistry
Nuclear magnetic resonance spectroscopy
021001 nanoscience & nanotechnology
Condensed Matter Physics
0104 chemical sciences
Electronic, Optical and Magnetic Materials
Amorphous solid
Crystallography
chemistry
Alkoxide
Ceramics and Composites
symbols
0210 nano-technology
Raman spectroscopy
Titanium
Subjects
Details
- ISSN :
- 00223093
- Volume :
- 170
- Database :
- OpenAIRE
- Journal :
- Journal of Non-Crystalline Solids
- Accession number :
- edsair.doi.dedup.....27f3da65e09e680c7104b889a39b6f61