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Comparative Resin Kinetics Using in Situ Fluorescence Measurements
- Source :
- Journal of Combinatorial Chemistry. 4:204-208
- Publication Year :
- 2002
- Publisher :
- American Chemical Society (ACS), 2002.
-
Abstract
- The aminolysis of a novel activated ester resin was utilized for kinetic study via continuous in situ fluorescence measurements. A variety of resin compositions (polystyrene, JandaJel, ArgoPore, TentaGel, NovaGel, and PEGA) and solvents (dimethylformamide, acetonitrile, tetrahydrofuran, 1,2-dichlorethane, and toluene) were tested to compare their effects on the reaction rate. A linear relationship between the reaction rate and (solvent polarity x swelling of resin) was elucidated for the aminolysis reaction.
- Subjects :
- Benzylamines
Kinetics
General Chemistry
Amides
Toluene
Fluorescence
Reaction rate
Resins, Synthetic
chemistry.chemical_compound
Aminolysis
chemistry
Polymer chemistry
Solvents
Combinatorial Chemistry Techniques
Dimethylformamide
Fluorometry
Polystyrene
Acetonitrile
Tetrahydrofuran
Nuclear chemistry
Subjects
Details
- ISSN :
- 15204774 and 15204766
- Volume :
- 4
- Database :
- OpenAIRE
- Journal :
- Journal of Combinatorial Chemistry
- Accession number :
- edsair.doi.dedup.....25e35c7f7005099e936f17e7c82dec4c