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Insight into Rare Structurally Characterized Homotrinuclear CuII Non-Symmetric Salamo-Based Complex
- Source :
- Crystals, Volume 11, Issue 2, Crystals, Vol 11, Iss 113, p 113 (2021)
- Publication Year :
- 2021
- Publisher :
- MDPI AG, 2021.
-
Abstract
- A rare homotrinuclear CuII salamo-based complex [Cu3(L)2(μ-OAc)2(H2O)2]·2CHCl3·5H2O was prepared through the reaction of a non-symmetric salamo-based ligand H2L and Cu(OAc)2·H2O, and validated by elemental analyses, UV-Visible absorption, fluorescence and infrared spectra, molecular simulation and single-crystal X-ray analysis techniques. It is shown that three CuII atoms and two wholly deprotonated ligand (L)2− moieties form together a trinuclear 3:2 (M:L) complex with two coordination water molecules and two bi-dentate briging μ-acetate groups (μ-OAc−). Besides, the Hirshfeld surface analysis of the CuII complex was investigated. Compared with other ligands, the fluorescent strength of the CuII complex was evidently lowered, showing that the CuII ions possess fluorescent quenching effect.
- Subjects :
- crystal structure
the Dmol3 module
010405 organic chemistry
Ligand
Chemistry
General Chemical Engineering
Infrared spectroscopy
Crystal structure
CuII complex
010402 general chemistry
Condensed Matter Physics
01 natural sciences
Fluorescence
0104 chemical sciences
Ion
Inorganic Chemistry
non-symmetric salamo-based ligand
Crystallography
Deprotonation
lcsh:QD901-999
Molecule
General Materials Science
lcsh:Crystallography
fluorescence prop erty
Absorption (chemistry)
Subjects
Details
- ISSN :
- 20734352
- Volume :
- 11
- Database :
- OpenAIRE
- Journal :
- Crystals
- Accession number :
- edsair.doi.dedup.....25ad3d4352feaa087256f3f74dea32c0