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The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride
- Source :
- Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 12, Pp 1323-1326 (2021)
- Publication Year :
- 2021
- Publisher :
- International Union of Crystallography, 2021.
-
Abstract
- The title complex, systematic name catena-poly[[[acetatochloridozinc(II)]-μ-(5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro[1,2,4]triazolo[1,5-a]pyrimidin-6-amine] monohydrate], {[Zn(C2H3O2)Cl(C15H15N5O)]·H2O} n , is the first coordination complex in which the neutral tetrahydrotriazolopyrimidine derivative acts as bridging ligand between two zinc molecules. As a result, polymeric chains of the coordination complex are found. The coordination of the zinc metal atom occurs with the lone pairs of the triazolo nitrogen atom and amino group. The positive charge of the zinc atom is compensated by the chlorine anion and deprotonated acetic acid. The coordination complex exists as a monohydrate in the crystalline phase. The water molecules bind neighbouring polymeric chains by the formation of O—H...O, O—H...Cl and N—H...O hydrogen bonds.
- Subjects :
- chemistry.chemical_classification
crystal structure
Hydrogen bond
polymeric coordination complex
chemistry.chemical_element
Bridging ligand
molecular structure
General Chemistry
Zinc
Condensed Matter Physics
Medicinal chemistry
Coordination complex
chemistry.chemical_compound
Chemistry
Deprotonation
chemistry
(5r,6r,7s)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-α]pyrimidin-6-aminozinc(ii)acetate-chloride
Furan
hirshfeld surface analysis
General Materials Science
Lone pair
QD1-999
Derivative (chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 77
- Issue :
- 12
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Accession number :
- edsair.doi.dedup.....237a0c1ce6ca4de1eda0643210ddc01f