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Bis(4-methylbenzylammonium) tetrabromidozincate
- Source :
- IUCrData, Vol 3, Iss 5, p x180648 (2018)
- Publication Year :
- 2018
- Publisher :
- International Union of Crystallography (IUCr), 2018.
-
Abstract
- The structure of the non-centrosymmetric organic–inorganic hybrid material, (C8H12N)2[ZnBr4], consists of two 4-methylbenzylammonium cations and one [ZnBr4]2− anion connected by N—H...Br and C—H...Br hydrogen bonds. The ZnII cation has a slightly distorted tetrahedral coordination environment. No π–π stacking interactions between the phenylene rings but C—H...π interactions towards them are observed. The structure was refined as a two-component inversion twin.
- Subjects :
- 010302 applied physics
crystal structure
biology
Hydrogen bond
Stacking
Crystal structure
non-centrosymmetric organic-inorganic hybrid material
010403 inorganic & nuclear chemistry
biology.organism_classification
01 natural sciences
0104 chemical sciences
chemistry.chemical_compound
Crystallography
C—H...π interactions
chemistry
0103 physical sciences
C—H...Br and N—H...Br hydrogen bondings
lcsh:QD901-999
Tetra
Ammonium
lcsh:Crystallography
Hybrid material
Zincate
Subjects
Details
- ISSN :
- 24143146
- Volume :
- 3
- Database :
- OpenAIRE
- Journal :
- IUCrData
- Accession number :
- edsair.doi.dedup.....2200520a3d9773f9932fb3228bc83246