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Effect of pressure on the properties of a NASICON Li1.3Al0.3Ti1.7(PO4)3 nanofiber solid electrolyte
- Source :
- Journal of Materials Chemistry A 9 (2021): 13688–13696. doi:10.1039/D1TA01143J, info:cnr-pdr/source/autori:La Monaca A.; Girard G.; Savoie S.; Demers H.; Bertoni G.; Krachkovskiy S.; Marras S.; Mugnaioli E.; Gemmi M.; Benetti D.; Vijh A.; Rosei F.; Paolella A./titolo:Effect of pressure on the properties of a NASICON Li1.3Al0.3Ti1.7(PO4)3 nanofiber solid electrolyte/doi:10.1039%2FD1TA01143J/rivista:Journal of Materials Chemistry A/anno:2021/pagina_da:13688/pagina_a:13696/intervallo_pagine:13688–13696/volume:9
- Publication Year :
- 2021
- Publisher :
- ROYAL SOC CHEMISTRY, ENGLAND, 2021.
-
Abstract
- We report the effect of pressure on a membrane made of dense electrospun NASICON-like Li1.3Al0.3Ti1.7(PO4)3 (LATP). The properties and performance of the pressed LATP nanofibers were investigated and compared with those of pristine LATP nanofibers. While the applied pressure affects the purity and homogeneity of LATP, it is beneficial for ionic transport across the solid electrolyte. The presence of impurity phases as well as the decrease of porosity results in a two order of magnitude higher ionic conductivity at room temperature (3 × 10−5 S cm−1) which is promising to replace bulk NASICON materials in energy storage devices.
- Subjects :
- Materials science
Renewable Energy, Sustainability and the Environment
Ionic bonding
02 engineering and technology
General Chemistry
Electrolyte
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
7. Clean energy
0104 chemical sciences
solid electrolyte
Membrane
Chemical engineering
Impurity
Nasicon
Nanofiber
nanofibers
Fast ion conductor
Ionic conductivity
General Materials Science
0210 nano-technology
Porosity
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Journal :
- Journal of Materials Chemistry A 9 (2021): 13688–13696. doi:10.1039/D1TA01143J, info:cnr-pdr/source/autori:La Monaca A.; Girard G.; Savoie S.; Demers H.; Bertoni G.; Krachkovskiy S.; Marras S.; Mugnaioli E.; Gemmi M.; Benetti D.; Vijh A.; Rosei F.; Paolella A./titolo:Effect of pressure on the properties of a NASICON Li1.3Al0.3Ti1.7(PO4)3 nanofiber solid electrolyte/doi:10.1039%2FD1TA01143J/rivista:Journal of Materials Chemistry A/anno:2021/pagina_da:13688/pagina_a:13696/intervallo_pagine:13688–13696/volume:9
- Accession number :
- edsair.doi.dedup.....21c806b7fcc26f386d16065b18ee3e8d
- Full Text :
- https://doi.org/10.1039/D1TA01143J