Switch from Anionic Polymerization to Coordinative Chain Transfer Polymerization: A Valuable Strategy to Make Olefin Block Copolymers

Authors :: Nicolas Baulu
Marvin Langlais
Robert Ngo
Julien Thuilliez
François Jean‐Baptiste‐dit‐Dominique
Franck D'Agosto
Christophe Boisson
Source :: Angewandte Chemie. 134
Publication Year :: 2022
Publisher :: Wiley, 2022.
Abstract: Anionic polymerization of butadiene or/and styrene is performed with lithium initiators, functional or not. The polymer chains are subsequently transferred to magnesium. The resulting polymeryl-magnesium compounds were combined with {(Me

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