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A [Mn18] wheel-of-wheels
- Source :
- Chemical Communications, Coletta, M, Tziotzi, T G, Gray, M, Nichol, G S, Singh, M K, Milios, C J & Brechin, E K 2021, ' A [Mn 18 ] wheel-of-wheels ', Chemical Communications, vol. 2021, no. 57, pp. 4122-4125 . https://doi.org/10.1039/D1CC00185J
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- A [Mn18] wheel of wheels is obtained from the reaction of MnBr2·4H2O and LH3 in MeOH. The metallic skeleton reveals two asymmetric [MnIII6MnII2] square wheels connected into a larger wheel via two MnII ions. Magnetic susceptibility and magnetisation data reveal competing exchange interactions, supported by computational studies.
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....20003d1829f7b4613e1cd280642a67b0
- Full Text :
- https://doi.org/10.1039/d1cc00185j