Qualitative and Quantitative Characterization of Generated Waste in Nouri Petrochemical Complex, Assaluyeh, Iran

In recent years, different petrochemical complexes have been established to produce aromatic compounds. Among them, Nouri Petrochemical Complex (NPC) is the largest producer of aromatic raw materials in the world, and is located in south of Iran. Environmental concerns have been raised in this region due to generation of different types of solid waste generated in the process of aromatics production, and subsequently, industrial waste characterization has been thoroughly considered. The aim of this study is qualitative and quantitative characterization of industrial waste generated in the aromatics production process and determination of the best method for industrial waste management. For this purpose, all generated industrial waste during the production process was determined using a checklist. Four main industrial wastes were identified as follows: spent industrial soil, spent catalyst, spent molecular sieves and spent N-formyl morpholine (NFM) solvent. The amount of heavy metals and organic compounds in these wastes were further measured in order to identify the nature and toxicity of such a dangerous compound. Then industrial wastes were classified based on lab analysis results as well as using different international lists of hazardous waste identification such as EPA, UNEP and Basel Convention. Finally, the best method of waste disposal is selected based on environmental, economic and technical aspects.
{"references":["P. Usapein, O. Chavalparit, \"Development of sustainable waste management toward zero landfill waste for the petrochemical industry in Thailand using a comprehensive 3R methodology: A case study,\" Waste Management & Research, vol. 32, no. 6, pp. 509-518, Jun 2014.","S. Zarinabadi, A. Samimi, \"Problems of hydrate formation in oil and gas pipes deals. Journal of American Science,\" vol. 8, no. 8, 2012.","B. Mokhtarani, M. RA. Moghaddam, N. Mokhtarani, H. J. Khaledi, \"Report: future industrial solid waste management in pars special economic energy zone (PSEEZ), Iran,\" Waste management & research, vol. 24, no. 3, pp. 283-288, Jun 2006.","ASTM B962 – 15. Standard Test Methods for Density of Compacted or Sintered Powder Metallurgy (PM) Products Using Archimedes' Principle, 2015.","ASTM D1976 – 12. Standard Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission Spectroscopy, 2007.","V. Mymrine, M. Ponte, H. Ponte, N. Kaminari, U. Pawlowsky, G. Solyon, \"Oily diatomite and galvanic wastes as raw materials for red ceramics fabrication,\" Construction and Building Materials, vol. 41, pp. 360-364, Apr 2013.","D. Eliche-Quesada, \"Reusing of Oil Industry Waste as Secondary Material in Clay Bricks,\" Journal of Mineral, Metal and Material Engineering, vol.1, pp. 29-39, Oct 2015.","D. Eliche-Quesada, F. Corpas-Iglesias, \"Utilisation of spent filtration earth or spent bleaching earth from the oil refinery industry in clay products,\" Ceramics International, vol. 40, no. 10, pp. 16677-16687, Des 2014.","M. Shahrabi-Farahani, S. Yaghmaei, S. Mousavi, F. Amiri, \"Bioleaching of heavy metals from a petroleum spent catalyst using Acidithiobacillus thiooxidans in a slurry bubble column bioreactor,\" Separation and Purification Technology, vol. 132, pp. 41-49, Aug 2014. \n[10]\tD. Jafarifar, M. Daryanavard, S. Sheibani, \"Ultra fast microwave-assisted leaching for recovery of platinum from spent catalyst. Hydrometallurgy,\" vol. 78, no. 3, pp. 166-171, Aug 2005.\n[11]\tD. Mishra, Y. H. Rhee, \"Current research trends of microbiological leaching for metal recovery from industrial wastes,\" Curr Res Technol Educ Topics Appl Microbiol Microb Biotechnol, vol. 2, pp. 1289-1292, 2010.\n[12]\t I. Asghari, S. Mousavi, F. Amiri, S. Tavassoli \"Bioleaching of spent refinery catalysts: A review,\" Journal of Industrial and Engineering Chemistry, vol. 19, no. 4, pp. 1069-81, Jul 2013. \n[13]\tS. Vyas, Y-P. Ting, \"Sequential biological process for molybdenum extraction from hydrodesulphurization spent catalyst,\" Chemosphere, 160, pp. 7-12, Oct 2016. \n[14]\t N. Su, H. Y. Fang, Z. H. Chen, F. S. Liu, \"Reuse of waste catalysts from petrochemical industries for cement substitution,\" Cement and Concrete Research, vol. 30, no. 11, pp. 1773-1783, Nov 2000. \n[15]\tK. Al-Jabri, M. Baawain, R. Taha, Z. S. Al-Kamyani, K. Al-Shamsi, A. Ishtieh, \"Potential use of FCC spent catalyst as partial replacement of cement or sand in cement mortars,\" Construction and Building Materials, pp. 77-81, Feb 2013."]}