Site Investigation and Remediation of Sulfate-Contaminated Groundwater Using Integrated Hydraulic Capture Techniques

Inorganic pollution is widespread in groundwater, and sulfate pollution is one of the important types, which has an important impact on the ecological environment and human health. Elevated concentrations of sulfate ion pollutants often come from the sewage discharge of chemical plants. This study takes a sulfate-contaminated site in Dongying City, Shandong Province, China, as the research object. Nine boreholes were arranged along the sewage discharge ditches in the site to collect and analyze soil samples and groundwater samples in layers. The concentration of pollutants and the change with depths were determined; the maximum concentration of sulfate ion was 10,330 mg L−1 in groundwater, and the maximum pollution depth was no more than 8 m. A hydraulic barrier was carried out to cut off the pollution sources. Based on a comprehensive understanding of the hydrogeological conditions and pollution degree of the site, the hydraulic capture technique was used to control the water pumping and injection volume, so that the scope of the pollution plume was gradually reduced. The pumping wells were arranged in the polluted area, and the water injection wells were arranged at the outer edge of the pollution zone. According to the calculation of the single well water inflow and influence radius, 28 pumping wells and 66 water injection wells were needed to be arranged on the site. The treatment process was divided into four stages according to the following steps: water pumping, water injection, stoppage of water injection, stoppage of water pumping, collecting water samples after the water level recovered, and the completion stage of treatment. The above process was repeated twice. Chemical precipitation was employed in the last step. The results of the remediation showed that the sulfate concentrations in 54 percent of the samples decreased significantly to less than 100 mg L−1, and the rest were between 100 and 200 mg L−1 after the treatment process. Two pumping wells with serious pollution were selected as long-term monitoring wells, and two-year continuous monitoring results showed that sulfate concentrations in the monitoring wells ranged from 110 to 220 mg L−1, indicating that integrated groundwater remediation techniques are more effective and more reliable than one single technique.