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Dioxygen activation with stable N-heterocyclic carbenes
- Source :
- Chemical communications (Cambridge, England). 55(11)
- Publication Year :
- 2019
-
Abstract
- Dioxygen activation with both cyclic (amino)(alkyl)carbenes and di(amino)carbenes at ambient temperature is described. Theoretical studies suggest that electron rearrangement from the doubly filled σ orbital of carbene carbon to its vacant p orbital through the π* antibonding orbital of 3O2 can be considered for Ccarbene-O bond formation.
- Subjects :
- chemistry.chemical_classification
010405 organic chemistry
Chemistry
Metals and Alloys
chemistry.chemical_element
General Chemistry
Electron
Bond formation
010402 general chemistry
Antibonding molecular orbital
01 natural sciences
Medicinal chemistry
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Atomic orbital
Materials Chemistry
Ceramics and Composites
Carbene
Carbon
Alkyl
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 55
- Issue :
- 11
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....1c7cf34dea8182854a7f318ef3f034b4