One Stone for Multiple Birds: A Versatile Cross-Linked Poly(dimethyl siloxane) Binder Boosts Cycling Life and Rate Capability of an NCM 523 Cathode at 4.6 V

Increasing working voltage is a promising way to increase the energy density of lithium-ion batteries. Cycling and rate performance deteriorated due to excessive electrolyte decomposition and uncontrolled formation of a cathode-electrolyte interface (CEI) layer at a high voltage. A new concept is proposed to construct a high-voltage-stable electrode-electrolyte interface. An elastomeric poly(dimethyl siloxane) (PDMS) binder is incorporated into the electrode to modify the LiNi