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CO, CO2 and CS2 activation by divalent ytterbium hydrido complexes
- Source :
- Chemical Communications, Chemical Communications, 2022, 58 (9), pp.1362-1365. ⟨10.1039/d1cc06449e⟩
- Publication Year :
- 2022
- Publisher :
- HAL CCSD, 2022.
-
Abstract
- International audience; Treatment of a divalent ytterbium hydride complex [(Tp(Ad,iPr))-Yb(H)(THF)] (Tp(Ad,iPr) = hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate) (1) with CO, CO2 and CS2 resulted in the formation of a divalent ytterbium ethenediolate complex [(Tp(Ad,iPr))Yb](2)(cis-OCH=CHO) (2), a formate complex [(Tp(Ad,iPr))Yb(kappa(2)-O2CH)(THF)] (3), and a trivalent ytterbium ethenetetrathiolate complex [(Tp(Ad,iPr))-Yb-III](2)(C2S4) (4), respectively. DFT calculations were carried out to elucidate the reaction profiles of complexes 3 and 4.
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Database :
- OpenAIRE
- Journal :
- Chemical Communications, Chemical Communications, 2022, 58 (9), pp.1362-1365. ⟨10.1039/d1cc06449e⟩
- Accession number :
- edsair.doi.dedup.....1ad391665ecb25524343b70acb357bf2
- Full Text :
- https://doi.org/10.1039/d1cc06449e⟩