Organometallic reactions in aqueous media Bismuth-mediated crossed aldol type reactions

Authors :: Yoon Joo Lee
Tak Hang Chan
Source :: Canadian Journal of Chemistry. 81:1406-1412
Publication Year :: 2003
Publisher :: Canadian Science Publishing, 2003.
Abstract: Bismuth metal, upon activation by zinc fluoride, can effect the crossed aldol reaction between α-bromocarbonyl compounds and aldehydes in aqueous media. The reaction was found to be regiospecific and syn-diastereoselective.Key words: bismuth, zinc fluoride, aldol reaction, regioselectivity, aqueous media.

Subjects :: Aqueous medium
Chemistry
Organic Chemistry
food and beverages
chemistry.chemical_element
General Medicine
General Chemistry
Catalysis
Bismuth
Metal
Dry media reaction
Zinc fluoride
chemistry.chemical_compound
Aldol reaction
visual_art
Polymer chemistry
visual_art.visual_art_medium
Organic chemistry

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