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Near-infrared emitting copper(I) complexes with a pyrazolylpyrimidine ligand: exploring relaxation pathways

Authors :
Nikita A. Shekhovtsov
Tatyana E. Kokina
Katerina A. Vinogradova
Andrey Y. Panarin
Marianna I. Rakhmanova
Dmitry Y. Naumov
Natalya V. Pervukhina
Elena B. Nikolaenkova
Viktor P. Krivopalov
Rafał Czerwieniec
Mark B. Bushuev
Source :
Dalton transactions (Cambridge, England : 2003). 51(7)
Publication Year :
2022

Abstract

Mononuclear copper(i) complexes demonstrate T1 → S0 phosphorescence in the near-infrared region associated with ligand-to-metal charge transfer. The most effective intersystem crossing channels are S6 → T7, S6 → T8 and S10 → T12.

Subjects

Subjects :
Inorganic Chemistry

Details

ISSN :
14779234
Volume :
51
Issue :
7
Database :
OpenAIRE
Journal :
Dalton transactions (Cambridge, England : 2003)
Accession number :
edsair.doi.dedup.....18e51c0850f55ca4507c64c7357f5a6a