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N-Heterocyclic carbene ligands bearing poly(ethylene glycol) chains: effect of the chain length on palladium-catalyzed coupling reactions employing aryl chlorides
- Source :
- Chemical Communications. 51:17382-17385
- Publication Year :
- 2015
- Publisher :
- Royal Society of Chemistry (RSC), 2015.
-
Abstract
- N-Heterocyclic carbenes bearing poly(ethylene glycol) chains of different lengths have been designed and employed as ligands in palladium-catalyzed coupling reactions. The catalyst system having longer chains was found to be highly efficient for Suzuki-Miyaura coupling and borylation reactions employing aryl chlorides under mild reaction conditions.
- Subjects :
- Boron Compounds
inorganic chemicals
Ligands
Borylation
Catalysis
Coupling reaction
Polyethylene Glycols
chemistry.chemical_compound
Benzyl Compounds
Polymer chemistry
Materials Chemistry
Organic chemistry
Molecule
Molecular Structure
Chemistry
Aryl
Biphenyl Compounds
Imidazoles
Metals and Alloys
General Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Palladium-catalyzed coupling reactions
Ethylene glycol
Carbene
Palladium
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 51
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....18e2114e0fe5f8a3a778249e95c50849